CALCULATION OF BOND ENERGIES OF O-H AT THE THIO(AMINE)ALKYLPHENOLS THE VALUES OF OXIDATION POTENTIALS AND THE KINETIC DATA

Terakh Elena Igorevna

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O-H bonds dissociation energy has been appraised in molecules of ortho-unreplaced and 2,6-di-tert-butylreplaced thio(amine)alkylphenols. The calculation was carried out according to phenols’ oxidation potentials on the base of correlated-regressive analysis as well as to kinetic data (constants of interaction speed between phenols and cumilperoxide radicals) by means of crossed parabolic method.

Keywords: phenol, thio(amine)alkylphenol, oxidation potential, bonds dissociation energy, reaction speed constant, correlated-regressive analysis, crossed parabolic method

( 412.88 kB ) ( 394.95 kB )

Issue: 7, 2012

Pages: 83 — 86

Downloads: 876