Synthesis and Photochemical Dehydrocyclization of 1,2-Dyarifethenes

Andriyenko O. S., Vasilyeva O. L., Rayda Vladimir Stepanovich

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The possibility of convenient preparative methods of synthesis of polycyclic aromatic hydrocarbons of foehn set by the way of arylating olefins with halogenarils in the presence of palladium salts and following photochemical dehydrocyclization of 1,2-dyarilethenes are explored. The conditions of receiving of 3, 4, 5-nuclear carbons with different position of substituents with good preparative outputs are found. The prospects of method for synthesis of hydrocarbons of foehn set is shown.

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Issue: 4, 2003

Series of issue: Science

Rubric: Chemistry

Pages: 45 — 49

Downloads: 979